Chapter 12 Radiation chemistry of acids, esters, anhydrides, lactones and lactams (pages 755–780): O. I. Micic and O. S. Gal
Chapter thirteen The electrochemistry of carboxylic acids and derivatives: Cathodic mark downs (pages 781–824): James P. Coleman
Chapter 14 Decarbonylation reactions of acid halides and aldehydes through chlorotris?(triphenylphosphine)rhodium(i) (pages 825–857): M. C. Baird
Chapter 15 Pyrolysis of acids and their derivatives (pages 859–914): R. Taylor
Chapter sixteen Transcarboxylation reactions of salts of fragrant carboxylic acids (pages 915–944): Josef Ratusky
Chapter 17 Micellar results upon deacylation (pages 945–1020): C. A. Bunton and L. S. Romsted
Chapter 18 The chemistry of thio acid derivatives (pages 1021–1062): J. Voss
Chapter 19 The synthesis of lactones and lactams (pages 1063–1330): James F. Wolfe and Michael A. Ogliaruso
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Additional resources for Acid Derivatives: Volume 2 (1979)
22. J. G. Burr, J. Phys. Chem, 61,1481 (1957). 23. G. E. Adams, J. H. Baxendale and R. D. Segwick. J. Phys. , 63,854 (1959). 24. R. H. Johnsen,J. Phys. , 63,2041 (1959). 25. Lj. Josimovic, J. Tepl? and 0. I. Mikid, J. Chem. 285 (1976). 26. B. Ayscough, K. P. K. Roy, Trans. Farad. ,67, 360 (1971). 27. S. LukaE, J. Tepl9 and K. Vacek, J. Chem. ,Faraday I, 68, 1337 (1973). 28. Lj. Josimovid and I. G. Draganid, Itit. J. Radiat. Phys. , 5,505 (1973) 29. M i a d and V. Markovid, Int. J. Radiat. Phys.
Otherreactions . ACKNOWLEDGMENTS . REFERENCES . . . . . . . . . . . . . . . . . 782 782 782 784 784 790 792 794 794 797 799 800 800 800 801 801 801 804 805 805 806 806 808 810 813 813 813 814 817 818 820 821 821 78 2 James P. Coleman 1. INTRODUCTION The past fifteen years have seen a tremendous expansion in the area of organic electrochemistry. With the advent of readily available, and relatively inexpensive, electronic equipment for carrying o u t electrochemical experiments, synthetic and physical organic chemists have gradually adopted electrochemical techniques for both synthetic and mechanistic organic studies.
Reproduced by permission of Acta Chem. Scand. half-wave potentials and limiting currents vs. pH for 13 and 14. In strongly acidic solution 13 shows a reduction wave which merges into the background in the pH range 2-5. The reduction is then discernible until about pH 6 when the nonreducible anion is formed. The 1-benzyl compound (14) shows similar behaviour except that it is reducible at slightly less negative potentials and the reduction is, therefore, observable throughout the pH range. The decreased limiting current in Figure 3 for 14 vs 13 is caused by a combination of lower concentration and lower diffusion coefficient for 14.