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S. Tager and H. N. Christensen, J. Arner. Chern. , 1972,94,968. P. A. Apgar and M. L. Ludwig, J. Arner. Chern. 94,964. D. A. Lightner and D. E. Jackman, J. Arner. Chern. , 1974,96,1938. G. Snatzke and H. Klein, Chern. , 1972,105,244. M. Julia, D. Mansuy and P. Detraz, Tetrahedron Letters, 1976,2141. D. A. Lightner and D. E. Jackman , Chern. , 1974,344. 35 16. 2 . I J 20. 1] hepl2-ene Class 3a Bi- and tricyclic compounds, especially decalins ' aJ( H + Me 3 1- 10 3 9 2 H H d6 o OAe H COOH : I HO-y-CH 3 I I I Ph H I.
6. 7. 8. 9. 10. IS i i i ! I . I I . I i ,H r-ry~HzCH2CH3 n. 0 I PhCO~ H 3C' i "CH 3 H 2-one. By CD (Inverse octanf I rule)  IS I i 15. (IR,55,6R)-(+) 6-methyl-6. 0 ] hexan- 2-one. By co rule) [3J (Inverse octant 16. (5)-1+) 1,3-dlmethyl-3benzoylplpendlne. Abs. X-ray  racemiC [7J O. Cervinka, A. Fabryova and J. Hajicek, Coil. Czech Chern. , 1974,39,1582. R. L. Coffin, R. S. Givens and R. G. Carlson, J. A m er. Chern. , 1974,96,7554. D. I. Schuster and R. H. Brown, Chern. , 1976, 28. R. Bucourt, Y.
IR,25)-(-) 2phenylcyclopentanol -OTs(-) C(2) o ~ Ph ~H2COPh , H-~-CH3 13. (2R,45H+) 4plperldlno -2 - phenylpenton- 2-01 6 16. (S) l-benzoyl-2- plperrdmopropane (+) (cyclohexone) (-) (MeOH) See p. A50. F. Morlacchi, V. Losacco and V. Tortorella, Gazzetta, 1975,105,349. N. Tangari and V. Tortorella, Chern. , 1975,71. M. Tramontini, L. Angiolini, C. Fouquey and J. Jacques, Tetrahedron, 1973,29,4183. C. J. Kim and H. C. Brown,!. Arner. Chern. , 1972, 94, 5051; H. B. Hopps, Diss. , 1962,23,439. M. Kato, M.