By J.O. Hirschfelder, Douglas Henderson
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Additional info for Chemical Dynamics: Papers in Honor of H. Eyring
Evaluation of spectral integration in ICP MS, At. , 13, 93-98 (1992). , Veillon, C. , Error propagation in isotopedilution analysis as determined by Monte Car10 simulation, Anal. , 66, 2829-2834 (1994). Annexes 41 Annex 2: Glossary of Terms and Abbreviations This glossary attempts to provide helpful descriptions of key terms referred to in the Guide. It does not necessarily adhere to internationally recognised definitions of these terms. Accuracy A quantity referring to the difference between the mean of a set of results or an individual result and the value that is accepted as the true value for the quantity measured.
In particular: 1. It is considered good practice to know the concentration of the spike (although this is not strictly necessary as the IDMS measurement is actually based on a natural calibration standard of the analyte). If a certified spike standard is unavailable, the concentration of the spike is determined by a ‘reverse’ IDMS measurement using the natural calibration standard. 2. It is necessary to know the isotopic abundances of the two isotopes in the unknown sample. For a few elements (Li, B, Pb, U, Sr, 0 s ) these vary significantly in nature and hence must be determined for the actual sample.
57, 1986-1988 (1985). , Hjelm, M. , Letter to the Editor - Reference methodology involving isotope dilutiodmass spectrometry, Clin. , 31, 167168 (1985). , 22, 530-533 (1987). , International Union of Pure and Applied Chemistry Technical Report Critical evaluation of the use and analysis of stable isotopes, Pure Appl. , 69, 1753-1828 (1997). , Mass Spectrometric Isotope Dilution Analysis, in Methods in Geochemiso, Smales, A. R. ), Interscience, New York (1960). J. , Precision mass spectrometric isotope dilution analysis, Nucl.