By International Society for the Philosophy of Chemistry; Joseph E. Earley, Sr.
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Additional info for Chemical Explanation (Annals of the New York Academy of Sciences, v. 988)
2 Two-Dimensional Compounds . . . . . . . . . . 3 Three-Dimensional Compounds . . . . . . . . . . 30 . 30 . 32 . . . 34 36 36 39 40 3 Physical Characterisation and Novel Effects . . . . . . . 5 Structural Investigations . . . . . Investigations Under Applied Pressure . Magnetic Field Effects . . . . . . Spectroscopy with Synchrotron Radiation Metal-Centred Light Effects . . . . . . . . . . . . . . . . . . . . . . . . . .
65 6 References . . . . . . . . . . . . . . . . 69 . . . . 61 List of Abbreviations and Symbols EPR HS LD-LISC LIESST LIOH LiPOH LiPTH LITH LS NIESST SCO ST T1/2 gHS Electron paramagnetic resonance High spin Ligand-driven light-induced spin change Light induced excited spin state trapping Light induced optical hysteresis Light-perturbed optical hysteresis Light perturbed thermal hysteresis Light induced thermal hysteresis Low spin Nuclear decay induced excited spin state trapping Spin crossover Spin transition Spin transition temperature (temperature of 50% conversion of all “SCO-active” metal centres) High spin molar fraction 1 Introduction The phenomenon of thermal spin crossover (SCO), though already well known in inorganic chemistry for more than seven decades, has developed in recent years to one of the most actively studied subjects in coordination chemistry [1–5].
Strong-Field LIESST (SF-LIESST) . . . . . . . . . Light-Induced Thermal and Optical Hysteresis (LITH/LIOH) . Light-Perturbed Thermal and Optical Hysteresis (LiPTH, LiPOH) Nuclear Decay Induced Excited Spin State Trapping (NIESST) . Ligand-Centred Light Effects . . . . . . . . . . Ligand-Driven Light-Induced Spin Change (LD-LISC) . . . Ring Open/Close Switching . . . . . . . . . . . . . . . 3 General Remarks . . . . . . . . . . . . . . 61 Mainz Model of Cooperative Elastic Interactions .