Chemical Physics of Intercalation by Albert Hérold (auth.), A. P. Legrand, S. Flandrois (eds.)

By Albert Hérold (auth.), A. P. Legrand, S. Flandrois (eds.)

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The domain of intercalation of sulfuric oleums is given in [21]. 9 in the Pauling scale), HF is a strongly polar molecule. It can react with F- ions to form linear (FHF)- anions, which are present in graphite hydrofluoric acid compounds. 6_5 for the 1st stage, which are true GIC with good electrical conductiv~ty [ 4]. On the other hand, liquid HF reacts rapidly with graphite under a pressure of gaseous fluorine at room temperature and forms C6sHFZ compounds 36 (s > Z). These phases contain HFZ ions lying between the graphene sheets.

Ubbelohde (pl-31) ; 2. A. Herold (323-421) ; 3. S. Dresselhaus and G. E. Fischer {481-532) ;5. S. B. A. LevY,D. S. Dresselhaus and G. Dresselhaus, Advances in Physics, Vol. 30, 2(1981) p139-326 F) A. Herold, 1st Int. R. C. Forsmann, T. Dziemianowicz, K. Leong, D. Carl, Synth. Met. 5(1983) 77-100 The International Conferences on GIC of La Napoule 1977, Provincetown 1980, Pont-a-Mousson 1983, Jerusalem 1987 will be called ISGIC 1, 2, 3 and 4, respectively. PART I 1. P. Boehm, R. Setton, E. Stumpp, Synth.

Therefore intercalation from a water solution is in principle not possible. This is completely verified for cations because the 2H+/H 2 potential is much higher than E~. 36V). According to Fuzellier [20], intercalation of HN03- ions solvated by HN03 and H20 molecules starts beyond a ponderal concentration of 60% in HN03' The case of H2S04 is discussed in [21]. e) Role of the acid strength and of the complex anion stability It is well known that only strong Bronsted acids and the corresponding ions can be intercalated.

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