By Y. Marcus, E. Yanir, A. S. Kertes
Equilibrium Constants of Liquid-Liquid Distribution Reactions, half III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents specializes in the compilation of equilibrium constants of varied compounds, equivalent to acids, ions, salts, and aqueous strategies.
The manuscript provides tables that express the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and different reactions within the natural section and extraction reactions of steel ions from aqueous suggestions. The e-book additionally states that the inorganic anions in those ideas are inappropriate, considering they don't participate in the extraction response.
The booklet examines tables that illustrate the distribution of inorganic acids, salts, and complexes among aqueous suggestions and solvents that experience oxygen donor atoms. Tables that convey the distribution of inorganic acids, salts, and complexes among aqueous suggestions and inert solvents that don't have donor atoms and infrequently applied as inert diluents also are awarded.
The manuscript is an important reference for readers and researchers attracted to the equilibrium constants of compounds.
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Additional info for Compound Forming Extractants, Solvating Solvents and Inert Solvents
25_, 1351 (1963). Extractant: 63S M METAL ION, AQ. benzene HA kerosene CONDITIONS, ORG. 63H/56W 63H/32T 63H/43S 63H/48J 63H/23H 63H/11G 21C 63H 63H 61H REF. 5 MA^ + M l ^ = 2 MAT MA. 50 TEMP. 47 LOG MAI + MAT MABr = MABr MA 2 = MA^" H + + S = HA-S + 2S = HA-S 2 + S = MS + M + A + A + A" = HA C1",A" M + MS H H H N03-,A- H 20 = H^O R E A C T I O N AQ. 3, MA 4 1 0 " - 1 0 4 _1 NaClO. 9 HA 2-14 H 20 H 20 in H 2S 0 4 CONDITIONS, ORG. 0 (mol. )in CC1 benzene benzene MA 2 in benzene MA 2 in benzene MA 2 in benzene HA in benzene pure benzene pure benzene octane HA in benzene 25-75% in benzene 25-75% + octane HA in benzene H 20 in benzene benzene CONDITIONS, 660 63S 57Ma 57Ma 57Ma 57Ma 57M/15L,] 02S 57M 57M 66H 51A, 52A 51A 63H 63H 63H 66H 65H REF.
25, 1351 (1963). Hogfeldt, E. , Svenk Kern. Tidskr. , 78_, 490 (1966). Olszer, R. , J. Inorg. Nucl. , 28, 1991 (1966). M. , J. Amer. Chem. S o c , 72_, 5170 (1950). R E A C T I O N 50K M METAL ION. CONDITIONS, AQ. CONDITIONS, ORG. REF.
Japan, 38, 1713 (1965). M. , Radiokhimiya 6^, 666 (1964). ) LOG Siekierski, S. , J. Inorg. Nucl. , 25_, 1351 (1963). R E A C T I O N 63S M METAL ION, 37 +3 +4 ++ + + A" = HA +4 Hg ++ Ligand; Ge Hg ++ Ligand. 0 22 0. 0 hexane toluene 57M/12D 25 -1. 64 57M/20M 25 -1. 00 _1 57M/15L,16L 25 57M/01H 66H 57M REF. -1. 02 ORG. 57M/98B M A 2 toluene HA in toluene toluene CONDITIONS, 25 4 AQ. -1. 5NaC104 CONDITIONS. 25 25 25 TEMP. -1. 03 -6. 63 -2. 2 LOG K MA 4 = MA7 MA 2 = MA^" Br~, A~ A + S = ATS" Ligand : IC1,A As Ge Hg Ligand Hg ++ Ligand M METAL ION, 38 Hantzsch, A.