N-Heterocyclic Carbenes in Transition Metal Catalysis and by Luigi Cavallo, Catherine S. J. Cazin (auth.), Catherine S.J.

By Luigi Cavallo, Catherine S. J. Cazin (auth.), Catherine S.J. Cazin (eds.)

N-Heterocyclic Carbenes in Transition steel Catalysis and Organocatalysis positive factors all catalytic reactions enabled by means of N-heterocyclic carbenes (NHCs), both without delay as organocatalysts or as ligands for transition steel catalysts. An explosion within the use of NHCs has been suggested within the literature in past times seven years making this finished evaluation hugely apropos.

The publication starts off with an introductory evaluate of NHCs which may were subtitled all you want to learn about NHCs. the most physique of the booklet is devoted to functions of NHCs in catalysis. as well as the good fortune tales of NHCs in metathesis, NHCs in go coupling and extra lately NHCs in organocatalysis, all different much less publicized parts also are lined. because the luck of NHCs is mostly attributed to their capability to stabilize steel centres, the inclusion of a bankruptcy at the decomposition of NHC catalysts is pertinent. The publication closes with a bankruptcy describing the functions of NHCs in commercial tactics, that's the 1st assurance of its type, and brings a different commercial context to this book.

Included during this book:

  • Historical points of NHCs
  • Synthetic pathways to NHC precursors, loose NHCs and complexes
  • Methods of characterisation of NHCs and similar complexes
  • Electronic homes of NHCs
  • Steric houses of NHCs and types for his or her description
  • NHCs for metathesis and cross-coupling reactions
  • NHCs as organocatalysts
  • NHC Transition-Metal mediated oxidations, additions to a number of bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions concerning CO, C-F and C-H bond activation, …
  • Decomposition of NHC-containing catalysts
  • Industrial functions regarding NHC-containing catalysts

N-Heterocyclic Carbenes in Transition steel Catalysis and Organocatalysis offers a clean view of NHCs because so much individuals are younger rising researchers within the box of homogeneous catalysis utilizing NHCs. This crew of individuals is complemented by way of hugely validated educational researchers and an industrialist. This ebook is accomplished, from the elemental beneficial properties of NHCs to the most recent advances, accordingly it really is appropriate for either the amateur and the expert.

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Altenhoff G, Goddard R, Lehmann CW, Glorius F (2004) J Am Chem Soc 126:15195–15201 73. Frey GD, Rentzsch CF, von Preysing D, Scherg T, Muehlhofer M, Herdtweck E, Herrmann WA (2006) J Organomet Chem 691:5725–5738 74. Leuthäußer S, Schwarz D, Plenio H (2007) Chem Eur J 13:7195–7203 75. Poater A, Cosenza B, Correa A, Giudice S, Ragone F, Scarano V, Cavallo L (2009) Eur J Inorg Chem 1759–1766 76. Hillier AC, Sommer WJ, Yong BS, Petersen JL, Cavallo L, Nolan SP (2003) Organometallics 22:4322–4326 77.

2) which is an active catalyst for the direct hydrogenation of 1-hexene, allylbenzene and cyclooctene. At higher temperatures (ca. 100°C) the activity of 11 is superior to 10. ) quantities of HBF4·Et2O act as co-catalyst, by enhancing the dissociation of PCy3 (through the formation of [PCy3H+][BF4−]) [9]. Similar behaviour was observed in the ­hydrogenation of 1-octene by [Ru(CO)(Cl)(Ph)(PCy3)(SIMes)], 12 [10]. [RuCl(H)(CO)(PPh3)(NHC)] (NHC = IMes, SIMes), 13, is more active for the hydrogenation of cyclooctene or cis- and trans-cyclododecene [11] due to the increased lability of PPh3 compared to PCy3.

The hydrosilylation of alkynes has also been studied using as catalysts Pt, Rh, Ir and Ni complexes. The improvement of the regioselectivity of the catalyst and the understanding of stereoelectronic factors that control it have been major incentives for the ongoing research. From numerous studies involving non-NHC catalysts, it has been established that there is a complex dependence of the product ratio on the type of metal, the alkyne, the metal coordination sphere, the charge (cationic versus neutral) of the catalytic complex and the reaction conditions.

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